环境样品中甲基汞的检测方法综述   总被引：1，自引：0，他引：1  

孙维萍  潘建明  翁焕新  朱利中  郑旻辉 《海洋学研究》2010,28(2):45-51

综述了常用的环境样品中甲基汞的检测方法和检测步骤,认为在实际的甲基汞检测过程中,选择或评价所选用检测方法的原则通常是,在确保检测限的基础上,首选考虑检测结果的精确度如何,而快捷方便、经济实惠的检测技术也是现实运用中的实际需要。作为定量检测,GC分别与AAS、AES、AFS的联用是目前较常用的技术,而与ICP-MS或ID-ICPMS的联用,在今后的实际检测中将得到更广泛的运用。生物传感器检测到的汞一般是生物可利用的汞,降低其检测限并将其作为对污染水体与沉积物检测的重要方法,也是今后研究的重点。总之,在人类对环境安全和身体健康日益重视的今天,发展高灵敏度、高准确度、快速方便和低成本的检测技术是未来甲基汞检测的重要发展方向。  相似文献   

不同预处理方法对南海东沙海域沉积物粒度的影响   总被引：1，自引：0，他引：1  

商和辉  林伟清 《海洋地质与第四纪地质》2010,(1)

通过采用不同方法对东沙沉积物样品进行了预处理,并采用综合法进行了粒度分析,以探讨东沙沉积物中碳酸盐和有机质对其粒度的影响。结果表明,去除有机质后沉积物的平均粒径和63～4μm粒径范围内的组分明显减小,有机质含量变化与平均粒径变化呈明显负相关,说明东沙沉积物中有机质的沉积是伴随细粒悬浮物质和胶体物质沉积下来的,且对细颗粒有明显的絮凝作用;去除碳酸盐后沉积物的平均粒径呈减小趋势,但粒径范围内组分含量的变化不明显,且碳酸盐含量的变化与沉积物粒径变化的关系也不甚密切。  相似文献   

基于粒子群优化算法的最大类间方差多阈值图像分割     

周晓伟  葛永慧 《测绘科学》2010,35(2):88-89,122

最大类间方差法是图像分割中一种常用的阈值分割方法,对于单阈值分割具有显著的效果,但是对于多阈值分割,计算复杂度大、耗时较多。本文将粒子群优化算法与最大类间方差法结合,提出了一种新的图像分割方法,该方法利用粒子群优化算法的寻优高效性,并由灰度图像的最大类间方差值作为适应值,搜索最优分割阈值,实现图像的多阈值分割。实验结果显示,新方法大大缩短了寻找最优阈值的时间,降低了运算复杂度,提高了图像分割速度,说明基于粒子群优化算法的图像分割算法是可行的、有效的。  相似文献   

Patterns of mixed siliciclastic‐carbonate sedimentation adjacent to a large dry‐tropics river on the central Great Barrier Reef shelf,Australia     

《Australian Journal of Earth Sciences》2013,60(5):665-683

The Great Barrier Reef represents the largest modern example of a mixed siliciclastic‐carbonate system. The Burdekin River is the largest source of terrigenous sediment to the lagoon and is therefore an ideal location to investigate regional patterns of mixed sedimentation. Sediments become coarser grained and more poorly sorted away from the protection of eastern headlands, with mud accumulation focused in localised ‘hot spots‘ in the eastern portion of embayments protected from southeast trade winds. The middle shelf has a variable facies distribution but is dominated by coarse carbonate sand. North of Bowling Green Bay, modern coarse carbonate sand and relict quartzose sand occur. Shore‐normal compositional changes show Ca‐enrichment and Al‐dilution seawards towards the reef, and shore‐parallel trends show Al‐dilution westwards (across bays) along a Ca‐depleted mixing line. Intermediate siliciclastic‐carbonate sediment compositions occur on the middle shelf due to the abundance of relict terrigenous sand, a pattern that is less developed on the narrow northern Great Barrier Reef shelf. Rates of sediment deposition from seismic evidence and radiochemical tracers suggest that despite the magnitude of riverine input, 80–90% of the Burdekin‐derived sediment is effectively captured in Bowling Green Bay. Over millennial time‐scales, stratigraphic controls suggest that sediment is being preferentially accreted back to the coast.  相似文献   

The complex variable reproducing kernel particle method for two-dimensional elastodynamics     

陈丽  程玉民 《海洋学报(英文版)》2010,29(9)

On the basis of the reproducing kernel particle method (RKPM), a new meshless method, which is called the complex variable reproducing kernel particle method (CVRKPM), for two-dimensional elastodynamics is presented in this paper. The advantages of the CVRKPM are that the correction function of a two-dimensional problem is formed with one-dimensional basis function when the shape function is obtained. The Galerkin weak form is employed to obtain the discretised system equations, and implicit time integration method, which is the Newmark method, is used for time history analysis. And the penalty method is employed to apply the essential boundary conditions. Then the corresponding formulae of the CVRKPM for two-dimensional elastodynamics are obtained. Three numerical examples of two-dimensional elastodynamics are presented, and the CVRKPM results are compared with the ones of the RKPM and analytical solutions. It is evident that the numerical results of the CVRKPM are in excellent agreement with the analytical solution, and that the CVRKPM has greater precision than the RKPM.  相似文献   

Sediment and particulate phosphorus characteristics in grassed waterways from row crop corn and alfalfa fields collected by manual University of Exeter samplers and automatic sampling     

John C. Panuska  Laura Ward Good  Peter A. Vadas  Dennis L. Busch  Asli Ozkaynak 《水文研究》2011,25(15):2329-2338

Phosphorus (P) export from agricultural lands above known threshold levels can result in adverse impacts to receiving water quality. Phosphorus loss occurs in dissolved and sediment‐bound, or particulate phosphorous (PP), forms, with the latter often dominating losses from row‐cropped systems. To target practices, land managers need good computer models and model developers need good monitoring data. Sediment monitoring data (e.g. radiometric finger printing and sediment P sorption capacity) can help identify sediment source areas and improve models, but require more sediment mass than is typically obtained by automatic sampling. This study compares a simple suspended sediment sampler developed at the University of Exeter (UE) with automatic sampling in intermittent channels draining corn and alfalfa fields. The corn field had a greater runoff coefficient (27%) than alfalfa (11%). No differences were found in enrichment ratios (sediment constituent/soil constituent) in PP (PP_ER) or percent loss on ignition (LOI_ER) between paired UE samplers on corn. The median LOI_ER for the UE samplers (1·9%) did not differ significantly (p > 0·13) from the automatic sampler (2·0%). The PP_ER from the UE samplers was on average 20% lower than the automatic samplers. A correlation (r² = 0·75) was found between sediment PP and % LOI from automatic samplers and UE samplers for particles < 50 µm, while for > 50 µm PP concentration did not change with changes in % LOI. Sediment ammonium‐oxalate extractable metals were similarly related to LOI, with the strongest correlation for iron (r² = 0·71) and magnesium (r² = 0·70). Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

A discrete particle representation of hillslope hydrology: hypothesis testing in reproducing a tracer experiment at Gårdsjön,Sweden     

Jessica Davies  Keith Beven  Lars Nyberg  Allan Rodhe 《水文研究》2011,25(23):3602-3612

Despite the long history of the continuum equation approach in hydrology, it is not a necessary approach to the formulation of a physically based representation of hillslope hydrology. The Multiple Interacting Pathways (MIPs) model is a discrete realization that allows hillslope response and transport to be simultaneously explored in a way that reflects the potential occurrence of preferential flows and lengths of pathways. The MIPs model uses random particle tracking methods to represent the flow of water within the subsurface alongside velocity distributions that acknowledge preferential flows and transition probability matrices, which control flow pathways. An initial realization of this model is presented here in application to a tracer experiment carried out in Gårdsjön, Sweden. The model is used as an exploratory tool, testing several hypotheses in relation to this experiment. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Experimental Investigation of Instantaneous Properties of Wave Slamming on the Plate   总被引：1，自引：0，他引：1  

任冰李雪临  王永学 《中国海洋工程》2007,21(3):533-540

The purpose of this paper is to investigate the instantaneous properties of wave slamming on the plate structure of an open structure.The advanced instantaneous measuring technique-Particle Image Velocimetry(PIV) is applied to acquire the instantaneous velocity field of wave slamming.From the cross-correlation analysis results of the images captured by the CCD camera,the flow fields of wave impacting on the structure are displayed visually,and the instantaneous whole-field fluid velocity vectors are obtained.The relation between the instantaneous peak impacting pressures and the instantaneous velocities of water particles is studied by probability analysis.  相似文献   

Optimum Sample Size to Detect Perturbation Effects: The Importance of Statistical Power Analysis – A Critique     

Marco Ortiz 《Marine Ecology》2002,23(1):1-9

Abstract. The current article describes statistical power analysis as an efficient strategy for the estimation of the optimum sample size. The principle aim is constructively to criticise and enrich the results presented by Mouillot et al. (1999) , who estimate the optimum sample size for evaluating possible perturbations. The authors did not make any reference to statistical power analysis, even though their objective clearly went beyond a simple stock evaluation to assess management strategies in a particular marine ecosystem. Surprisingly, they proposed (a priori) an ANOVA design to test a hypothesis considering both space and temporal scales. However, the authors did not cover important topics related with power analysis and the precautionary principle, both used into environment impact assessment programmes for marine ecosystems. Based on their results and on statistical power analysis, it is demonstrated that the variability (dispersion statistics), a key factor they used to estimate the sample size, is less relevant than the magnitude of perturbation (effect size). Therefore, a greater effort must be devoted to estimate the effect size of a particular phenomenon rather than a desired variability.  相似文献   

栉孔扇贝大量死亡的流行病学调查研究   总被引：1，自引：0，他引：1  

张维翥  吴信忠  孙敬锋  李登峰 《海洋学报》2006,28(5):90-100

2001~2003年,对养殖的栉孔扇贝进行了较系统地流行病学调查研究.以栉孔扇贝养殖集中海区长岛县亚美扇贝养殖场为定点调查和样品采集点.调查内容主要包括栉孔扇贝各养殖期的死亡率和可疑病原生物检测,同时对pH、溶解氧、温度、盐度等环境理化因子进行连续监测.调查结果显示:栉孔扇贝在养殖初期幼贝阶段死亡率较低,随后死亡率逐渐升高,至8月24日月死亡率达最高点71%.9月份以后死亡率开始下降.至10月份累积死亡率达90%以上.对环境理化因子的调查显示,pH、溶解氧、盐度的变化幅度不大,与扇贝死亡率无明显相关性;温度变化与死亡率似有一定的相关性,即高温(月平均23℃以上)可能是养殖栉孔扇贝重要的环境胁迫因子.通过对可疑致病性生物因子的调查研究及病理学观察表明,栉孔扇贝在养殖过程中可感染多种微生物,其中原核微生物类立克次体(RLO)在养殖过程各生长阶段均可检出,其感染率和感染强度与扇贝死亡率呈现一致的趋势.在病原病理检测中,发现RLO的大量感染与组织细胞严重病理损伤密切相关.在病原生物检测过程中,除RLO以外还发现有类枝原体原核生物(MLO)和类病毒(VLP)寄生.RLO的人工感染实验结果说明RLO是栉孔扇贝重要的病原菌.结合感染率和死亡率、感染强度和组织病理学的相关性以及感染实验的结果分析,认为类立克次体(RLO)可能是栉孔扇贝养殖过程中大量死亡的主要致病因子.  相似文献